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A vanadium(IV) pyrazolate metal-organic polyhedron with permanent porosity and adsorption selectivity
A W Augustyniak1, M Fandzloch, M Domingo
1Institute of Public Health and Environmental Protection, Batystowa 1B, 02-835 Warsaw, Poland. adam.augustyniak1@gmail.com.
Chemical Communications (Cambridge, England)
|August 21, 2015
Abstract:
A vanadium(IV) pyrazolate-based open metal-organic polyhedron of [V3(μ3-O)O(OH)2(μ4-BPD)1.5(μ-HCOO)3] (BDP = benzene-1,4-bipyrazolate) formulation gives rise to a porous crystal structure exhibiting micro and mesoporosity which is useful for selective adsorption of gases.
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