Crystal structure of 2,2'-bis-[(2-chloro-benz-yl)-oxy]-1,1'-bi-naphthalene
Rajamani Raja1, Mani Jayanthi2, Perumal Rajakumar2
1Department of Physics, Presidency College (Autonomous), Chennai 600 005, India.
Abstract:
In the title binaphthyl compound, C34H24Cl2O2, the dihedral angle between the two naphthyl ring systems (r.m.s. deviations = 0.016 and 0.035 Å) is 76.33 (8)°. The chloro-phenyl rings make dihedral angles of 58.15 (12) and 76.21 (13)° with the naphthyl ring to which they are linked. The dihedral angle between the planes of the two chloro-phenyl rings is 27.66 (16)°. In the crystal, C-H⋯O hydrogen bonds link mol-ecules into chains propagating along [1-10]. The chains are linked by C-H⋯π inter-actions, forming a three-dimensional framework.
More Related Videos
06:44From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
19:58Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Related Concept Videos
Structure of Benzene: Molecular Orbital Model
Nomenclature of Aromatic Compounds with Multiple Substituents
For disubstituted benzene derivatives, with two groups attached to the benzene ring, three constitutional isomers are possible. For example, consider dimethyl benzene, often called xylene, where the second methyl group can be substituted at the second, third, or fourth carbon. The relative position of the substituents is represented by prefixes ortho, meta, or...
Structure of Benzene: Kekulé Model
He proposed that benzene has a cyclic structure of six carbon atoms attached to one hydrogen atom each, with three alternating pi bonds.
Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Nomenclature of Aromatic Compounds with a Single Substituent
Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism
