Related Experiment Video
Updated: Mar 29, 2026

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
Published on: May 9, 2014
Spontaneous self-assembly and disassembly of colloidal gold nanoparticles induced by tetrakis(hydroxymethyl)
Christopher P Gulka1, Alexis C Wong1, David W Wright1
1Department of Chemistry, Vanderbilt University, Station B 351822, Nashville, TN 37235-1822, USA. David.Wright@vanderbilt.edu.
Abstract:
Upon reacting with tetrakis(hydroxymethyl) phosphonium chloride, 15 nm citrate gold nanoparticles rapidly assemble into linear chains, followed by slowly disassembling into monodisperse components. This work highlights the first example of (31)P NMR on gold particles of this size and suggests that the phosphonium is oxidized on-particle, contributing to particle disassembly.
Related Concept Videos
The Colloidal State
Colloidal precipitates
Colloids

