Ion current rectification in funnel-shaped nanochannels: Hysteresis and inversion effects

Leon Rosentsvit1, Wei Wang2, Jarrod Schiffbauer1

  • 1Faculty of Mechanical Engineering, Micro- and Nanofluidics Laboratory, Technion-Israel Institute of Technology, Technion City 32000, Israel.

Summary

Ion current rectification inversion occurs in funnel-shaped nanochannels above a threshold voltage. This phenomenon arises from a shift in system resistance control from internal to external ion concentration polarization, also causing hysteresis.

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