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Ion current rectification in funnel-shaped nanochannels: Hysteresis and inversion effects
Leon Rosentsvit1, Wei Wang2, Jarrod Schiffbauer1
1Faculty of Mechanical Engineering, Micro- and Nanofluidics Laboratory, Technion-Israel Institute of Technology, Technion City 32000, Israel.
The Journal of Chemical Physics
|December 17, 2015
Summary
Ion current rectification inversion occurs in funnel-shaped nanochannels above a threshold voltage. This phenomenon arises from a shift in system resistance control from internal to external ion concentration polarization, also causing hysteresis.
Area of Science:
- Nanofluidics
- Electrochemistry
- Physical Chemistry
Background:
- Ion current rectification is crucial for nanopore applications.
- Previous studies focused on specific voltage regimes or channel geometries.
- Understanding rectification inversion in funnel-shaped nanochannels is key.
Purpose of the Study:
- To investigate ion current rectification inversion in funnel-shaped nanochannels.
- To identify the threshold voltage for rectification inversion.
- To elucidate the underlying mechanisms of rectification inversion and hysteresis.
Main Methods:
- Experimental observation of ion current rectification in funnel-shaped nanochannels.
- Voltage-dependent current measurements.
- Analysis of transient current and hysteresis effects.
Main Results:
- Ion current rectification inversion observed above a threshold voltage.
- Threshold voltage corresponds to the transition from under-limiting to over-limiting current.
- System resistance shifts from intra-channel to external concentration polarization control.
- Significant hysteresis effects observed due to residual concentration polarization.
Conclusions:
- Ion current rectification inversion is a voltage-dependent phenomenon in funnel-shaped nanochannels.
- The inversion mechanism involves a transition in dominant resistance control.
- Hysteresis effects are linked to concentration polarization dynamics and voltage scan rates.
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