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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Crystal structure of (RS)-(4-chloro-phen-yl)(pyridin-2-yl)methanol
Badiadka Narayana1, Balladka K Sarojini2, Hemmige S Yathirajan3
1Department of Studies in Chemistry, Mangalore University, Mangalagangothri 574 199, India.
Abstract:
In the title racemic compound, C12H10ClNO, the dihedral angle between the benzene and pyridine rings is 74.34 (6)°. In the crystal, the mol-ecules are linked by O-H⋯N hydrogen bonds, forming zigzag C(5) [001] chains in which alternating R- and S-configuration mol-ecules are related by c-glide symmetry. In addition, inversion-related pairs of mol-ecules are linked into dimers by pairs of weak C-Cl⋯π(pyrid-yl) inter-actions, which link the hydrogen-bonded chains into (100) sheets. Structural comparisons are drawn with a number of related compounds.
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