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Updated: Mar 25, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
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Published on: February 11, 2012

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A niobium-necked cluster [As3Nb(As3Sn3)](3-) with aromatic Sn3(2-) 

Fu-Xing Pan1, Cong-Qiao Xu, Lei-Jiao Li

  • 1State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, China. szm@ciac.ac.cn.

Dalton Transactions (Cambridge, England : 2003)
|February 25, 2016
PubMed
Summary

A novel ternary cluster compound, [As3Nb(As3Sn3)](3-), was synthesized featuring a niobium atom bonded to arsenic and tin ligands. This unique structure exhibits sigma-aromaticity in its tin component, offering new insights into Zintl phase chemistry.

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