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Supramolecular pathway selection of perylenediimides mediated by chemical fuels
Jorge Leira-Iglesias1, Alessandro Sorrenti1, Akihiro Sato1
1Institut de Science et d'Ingénierie Supramoléculaires (ISIS) UMR 7006, Université de Strasbourg, CNRS & icFRC, 8 allée Gaspard Monge, 67000 Strasbourg, France. hermans@unistra.fr.
Abstract:
We demonstrate supramolecular pathway selection of a perylenediimide derivative in aqueous solution using chemically fueled redox reactions to control assembly/disassembly cycles. The number and frequency of cycles affect the nucleation and growth process, providing control over the size and internal order of the resulting self-assembled structures.
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