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Updated: Mar 18, 2026

Hierarchical and Programmable One-Pot Oligosaccharide Synthesis
Published on: September 6, 2019
Syntheses and Potato Tuber-inducing Activities of Unnatural Long-chain OPC-9:0 and OPC-10:0
H Toshima1, Y Takano1, A Ichihara1
1a Department of Bioscience and Chemistry, Hokkaido University.
Abstract:
The unnatural long-chain OPCs, OPC-9:0 and OPC-10:0, were respectively synthesized from the ethyl esters of OPC-7:0 and OPC-8:0. C2-carbon elongation was achieved via alkylation of the enolate of tert-butyl acetate. The potato tuber-inducing activity of OPC-10:0, as well as OPC-8:0, -6:0 and -4:0, was similar to that of jasmonic acid. OPC-9:0 also exhibited weak tuber-inducing activity.
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