A colorimetric sensor for the selective detection of fluoride ions
Chin-Feng Wan1, Jiun-Ly Chir2, An-Tai Wu2
1Department of Medical Applied Chemistry, Chung Shan Medical University, Taichung City, 40201, Taiwan.
Abstract:
A colorimetric receptor L was prepared. Receptor L can selectively sense F- based on distinct color changes among a series of ions. It can selectively sense F- through an intramolecular hydrogen bond interaction. A Job plot indicated a 1:1 complexation stoichiometry between receptor L and F- . The association constant for L-F- in CH3 CN was determined as 9.70 × 104 M-1 using a Stern-Volmer plot.
Related Concept Videos
Fluorescence and Phosphorescence: Instrumentation
1.8K
Fluorometers and spectrofluorometers are two types of instruments used for measuring molecular fluorescence. These instruments differ in how they select excitation and emission wavelengths and the type of light sources they utilize. Fluorometers use absorption interference filters to choose excitation and emission wavelengths. The excitation source in a fluorometer is typically a low-pressure mercury vapor lamp that emits intense lines distributed throughout the ultraviolet and visible regions.
1.8K
Photoluminescence: Applications
1.2K
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
1.2K
Immunofluorescence Microscopy
14.4K
A fluorescence microscope uses fluorescent chromophores called fluorochromes, which can absorb energy from a light source and then emit this energy as visible light. Fluorochromes include naturally fluorescent substances (such as chlorophylls) and fluorescent stains that are added to the specimen to create contrast. Dyes such as Texas red and FITC are examples of fluorochromes. Other examples include the nucleic acid dyes 4’,6’-diamidino-2-phenylindole (DAPI), and acridine orange.
14.4K


