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4D-π-1A type β-substituted ZnII-porphyrins: ideal green sensitizers for building-integrated photovoltaics
A Covezzi1, A Orbelli Biroli2, F Tessore1
1Department of Chemistry, University of Milan, INSTM Research Unit, Via C. Golgi 19, 20133 Milano, Italy. gabriele.dicarlo@unimi.it.
Abstract:
Two novel green β-substituted ZnII-porphyrins, G1 and G2, based on a 4D-π-1A type substitution pattern have been synthesized. Their enhanced push-pull character, by reduction of H-L energy gaps, promotes broadening and red-shifting of absorption bands. The effective synthetic pathway and the remarkable spectroscopic properties make G2 ideal for BIPV application.
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