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Programmable and reversible plasmon mode engineering.

Ankun Yang1, Alexander J Hryn1, Marc R Bourgeois2

  • 1Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208.

Proceedings of the National Academy of Sciences of the United States of America
|December 3, 2016
PubMed
Summary
This summary is machine-generated.

Aluminum nanoparticle arrays in elastomers enable tunable, ultranarrow plasmon resonances in the visible spectrum. Stretching dynamically controls particle spacing, optimizing optical responses for advanced sensing and nanolasers.

Keywords:
flexible substrateslattice plasmonsmode engineeringnanoparticlesplasmonics

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Area of Science:

  • Plasmonics
  • Nanophotonics
  • Materials Science

Background:

  • Plasmonic nanostructures enhance optical fields and offer narrow linewidths, crucial for many applications.
  • Achieving actively engineered, ultranarrow resonances across the visible spectrum within a single system remains a challenge.

Purpose of the Study:

  • To demonstrate active engineering of ultranarrow plasmon resonances in the visible regime.
  • To explore the use of aluminum nanoparticle arrays in elastomers for tunable optical responses.

Main Methods:

  • Fabrication of aluminum nanoparticle arrays embedded in an elastomeric slab.
  • Utilizing mechanical stretching to tune particle spacing and optical properties.
  • Investigating the interplay between diffraction modes and single-particle plasmon resonances (dipolar/quadrupolar).

Main Results:

  • Achieved high-quality plasmon resonances with linewidths as narrow as 3 nm.
  • Demonstrated resonances at wavelengths inaccessible to conventional plasmonic materials.
  • Showcased selective access and optimization of dipolar or quadrupolar lattice modes via dynamic modulation of particle spacing.

Conclusions:

  • Programmable plasmon modes in stretched aluminum nanoparticle arrays offer real-time tunability.
  • These tunable materials are promising for plasmon-enhanced molecular sensing and plasmonic nanolasers.
  • Opens new avenues for integrating plasmonics with flexible electronics.