Metallacyclopentadienes: synthesis, structure and reactivity.
Wangyang Ma1, Chao Yu1, Tianyang Chen1
1Beijing National Laboratory for Molecular Sciences, MOE Key Laboratory of Bioorganic Chemistry and Molecular Engineering, College of Chemistry, Peking University, Beijing 100871, China. wx_zhang@pku.edu.cn.
Chemical Society Reviews
|January 26, 2017
Summary
Metallacyclopentadienes are versatile five-membered metallacycles with diverse applications. This review covers their synthesis, structure, reactivity, and use in organic and polymer chemistry.
Area of Science:
- Organometallic Chemistry
- Coordination Chemistry
- Synthetic Organic Chemistry
Background:
- Metallacyclopentadienes are key five-membered metallacycles with two M-C(sp2) bonds.
- They serve as reactive intermediates and precursors in various chemical transformations.
- Their unique structure has garnered significant attention for decades.
Purpose of the Study:
- To comprehensively review metallacyclopentadienes across the periodic table.
- To summarize their synthesis, structure, and reactivity.
- To highlight applications in organic and polymer chemistry.
Main Methods:
- Systematic review of literature on metallacyclopentadienes.
- Analysis of synthesis, structural features, and reactivity patterns.
- Compilation of applications in synthetic and polymer chemistry.
Main Results:
- Detailed overview of s-, p-, d-, and f-block metallacyclopentadienes.
- Summary of their diverse synthetic routes and structural motifs.
- Compilation of their utility in organic synthesis and polymer development.
Conclusions:
- Metallacyclopentadienes are crucial in modern chemistry.
- This review facilitates the design of novel metallacycles.
- It aims to accelerate advancements in metallacyclic chemistry.
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