Carbon-dot-based dual-emission silica nanoparticles as a ratiometric fluorescent probe for Bisphenol A

A simple and effective strategy for designing a ratiometric fluorescent nanosensor is described in this work. A carbon dots (CDs) based dual-emission nanosensor for Bisphenol A (BPA) was prepared by coating CDs on the surface of dye-doped silica nanoparticles. The fluorescence of dual-emission silica nanoparticles was quenched in hydrochloric acid by potassium bromate (KBrO₃) oxidation; BPA inhibited KBrO₃ oxidation, resulting in the ratiometric fluorescence response of dual-emission silica nanoparticles. Several important parameters affecting the performance of the nanosensor were investigated and optimized. The detection limit of this nanosensor was 0.80ng mL^-1 with a linear range from 10 to 500ng mL^-1. This was applied successfully to determine BPA in the leached solution of different plastic products with satisfactory results.