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Nanoscale Inhomogeneities Mapping in Ga-Modified Arsenic Selenide Glasses.

Ya Shpotyuk1,2, S Adamiak3, A Dziedzic3

  • 1Center for Innovation and Transfer of Natural Sciences and Engineering Knowledge, Faculty of Mathematics and Natural Sciences, University of Rzeszow, 1, Pigonia Str., 35-959, Rzeszow, Poland. yashpotyuk@gmail.com.

Nanoscale Research Letters
|February 8, 2017
PubMed
Summary

Nanoindentation mapping reveals nanoscale inhomogeneities in gallium-modified arsenic selenide (As2Se3) glasses. Gallium additions enhance nanohardness and Young

Keywords:
Arsenic selenide glassCrystallizationNanoindentationPhase separation

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Solid State Chemistry

Background:

  • Arsenic selenide (As2Se3) glasses are known for their optical properties.
  • Gallium (Ga) modification can alter the structural and mechanical properties of chalcogenide glasses.
  • Understanding nanoscale properties is crucial for advanced material applications.

Purpose of the Study:

  • To map nanoscale inhomogeneities in Ga-modified As2Se3 glasses.
  • To investigate the effect of Ga additions on the mechanical properties of As2Se3 glass.
  • To explore the utility of nanoindentation for characterizing such materials.

Main Methods:

  • Nanoindentation using a Berkovitch-type diamond tip.
  • Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM) for visualization.
  • Compositional analysis of Ga-modified As2Se3 alloys (Ga_x(As0.40Se0.60)100-x).

Main Results:

  • Structural inhomogeneities were detected in Ga_x(As0.40Se0.60)100-x alloys with >3 at.% Ga.
  • Ga2Se3 nanocrystallites were visualized within the Ga-modified glasses.
  • Ga additions increased nanohardness and Young's modulus.
  • A bifurcation trend in mechanical properties was observed in crystallized-decomposed Ga5(As0.40Se0.60)95 alloy.

Conclusions:

  • Nanoindentation is effective for mapping nanoscale inhomogeneities in Ga-modified As2Se3 glasses.
  • Gallium incorporation leads to the formation of Ga2Se3 nanocrystallites and enhances mechanical properties.
  • The observed bifurcation trend highlights the complex interplay between composition, structure, and mechanical response in these alloys.