Electrostatically Active Polymer Hybrid Aerogels for Airborne Nanoparticle Filtration

The role of electrostatic force on separation of airborne nanoparticles is evaluated in this work by considering a hybrid monolithic aerogel of syndiotactic polystyrene (sPS) and polyvinylidene fluoride (PVDF). The sPS part accounts for open pore structures in the monolith, while the PVDF chains contribute spontaneous polarity for particle capture by the electrostatic force. The hybrid aerogels are fabricated by thermoreversible gelation of sPS from a solution with PVDF in tetrahydrofuran followed by supercritical drying of the gel. sPS is present as the δ-form clathrate crystalline phase and PVDF as α- and γ-form crystalline phases in the hybrid. The presence of PVDF induces significant static charges on the surfaces of hybrid aerogels. The filtration efficiency is determined by passing airborne NaCl nanoparticles with diameter in the range 25-150 nm through the filter media. The experimental data reveal that air permeability of the hybrid system (∼10^-10 m²) is close to that of sPS monoliths. The hybrid materials show filtration efficiency ≥99.999% in comparison to 98.889% observed for a sPS monolith with the same solid content.