Metal-ion induced ferromagnetic polarization in a mixed-spin system
Li Yang1, Jing Li, Tian-Cheng Pu
1State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China. yousong@nju.edu.cn.
Abstract:
Three new 3d-3d heterometallic complexes, [CuMII(hmb)6(OH)]ClO4·H2O (M = Zn (1), Ni (2) and Co (3)) (Hhmb = 2-hydroxy-3-methoxy-benzaldehyde), have been synthesized. Structural analysis reveals that the three complexes are isostructural. Three CuII ions are in a perfect trigonal geometrical frustration and form a tetrahedral frustrated system with the introduced fourth ion ZnII/NiII/CoII. Magnetic studies indicate the antiferromagnetic coupling between metal ions in all 1, 2 and 3. Due to the geometrical frustration, spin-frustrated magnetism is also a typical feature of 1-3 and the magnetostructural correlation is far more complicated than their structures. The detailed magnetic investigation found that the ground state spin of 2 cannot be simply determined by the antiferromagnetically linear arrangement of spins, because the strong antiferromagnetic coupling between CuII and NiII ions quenches the spin frustration and ferromagnetically polarizes the spins of the [Cu] unit. Contrarily, the antiferromagnetic coupling between CuII and CoII ions is not strong enough in 3, so there is no similar behaviour compared to 2.
More Related Videos
Related Concept Videos
Ferromagnetism
Valence Bond Theory
Diamagnetism
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
Paramagnetism
Atomic Nuclei: Nuclear Magnetic Moment


