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Expanding applications of SERS through versatile nanomaterials engineering.

M Fernanda Cardinal1, Emma Vander Ende, Ryan A Hackler

  • 1Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. fernanda.cardinal@northwestern.edu emmavanderende2014@u.northwestern.edu ryan.hackler@northwestern.edu mcanally@u.northwestern.edu pstair@northwestern.edu schatz@northwestern.edu vanduyne@northwestern.edu.

Chemical Society Reviews
|June 23, 2017
PubMed
Summary

This review explores enhancing Surface-Enhanced Raman Scattering (SERS) spectroscopy by focusing on plasmonic substrate quality and molecule localization. Optimizing these factors is key for advancing SERS applications in chemistry and biology.

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Area of Science:

  • Analytical Chemistry
  • Materials Science
  • Spectroscopy

Background:

  • Surface-Enhanced Raman Scattering (SERS) spectroscopy is a powerful analytical tool for diverse fields.
  • Its application expansion relies on plasmonic substrate quality and analyte localization.
  • Understanding nanoscale chemical processes requires optimized SERS techniques.

Purpose of the Study:

  • To review recent advancements in SERS spectroscopy.
  • To highlight the importance of plasmonic substrate quality and molecule localization.
  • To propose future research directions by integrating disparate SERS fields.

Main Methods:

  • Quantifying SERS distance dependence.
  • Characterizing substrate performance and quality.
  • Developing substrates for UV plasmonics and short-distance capture.

Main Results:

  • Recent work quantifies SERS distance dependence.
  • Key factors for substrate characterization and evaluation are identified.
  • Substrate development enables UV plasmonics and optimized analyte-surface interactions.

Conclusions:

  • Synergistic integration of SERS fields can yield new research directions.
  • Challenges remain in applying SERS for in situ catalysis and biosensing.
  • Further research is needed for nanoscale chemical process understanding using SERS.