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Updated: Feb 26, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
Published on: March 20, 2017
Accessing Low-Valent Inorganic Cations by Using an Extremely Bulky N-Heterocyclic Carbene
Matthew M D Roy1, Paul A Lummis1, Michael J Ferguson1
1Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, AB, T6G 2G2, Canada.
Abstract:
The extremely bulky N-heterocyclic carbene (NHC), ITr (ITr=[(HCNCPh3 )2 C:]) featuring sterically shielding umbrella-shaped trityl (CPh3 ) substituents was prepared. This NHC features the highest percent buried volume (%Vbur ) to date, and was used to form a thermally stable quasi one-coordinate thallium(I) cation [ITr-Tl]+ . This TlI adduct and the corresponding lithium complex [ITr⋅Li(OEt2 )]+ are versatile "all-in-one" transmetalation/ligation reagents for preparing low-coordinate inorganic species inaccessible by pre-existing routes.
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