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Updated: Feb 23, 2026

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Fabrication of Periodic Gold Nanocup Arrays Using Colloidal Lithography
Published on: September 2, 2017
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Nanoporous gold assemblies of calixarene-phosphine-capped colloids
Christian Schöttle1, Ezra L Clark, Audrey Harker
1Department of Chemical and Biomolecular Engineering, University of California at Berkeley, Berkeley, California 94720, USA. askatz@berkeley.edu.
Abstract:
The synthesis of high surface-area colloidal assemblies of calixarene-phosphine-capped nanoporous gold is reported under reductive electrochemical conditions. These materials uniquely exhibit a remarkably thin wall thickness down to 10 nm, while possessing pore sizes on the order of up to hundreds of nanometers, which can be controlled via choice of organic ligand.

