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Updated: Feb 21, 2026

Preparation of N-2-alkoxyvinylsulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
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Trityl-based alkoxyamines as NMP controllers and spin-labels

Gérard Audran1, Elena G Bagryanskaya2,3, Paul Brémond1

  • 1Aix-Marseille Univ, CNRS, ICR, UMR 7273, case 551, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20 France.

Polymer Chemistry
|October 10, 2017
PubMed
Summary

Researchers developed the first spin-labelled alkoxyamines by attaching trityl radicals. These novel compounds are effective initiators for nitroxide-mediated polymerization (NMP), demonstrating high biradical yields.

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