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Origami Inspired Self-assembly of Patterned and Reconfigurable Particles
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Self-Assembly of Patchy Particles.

Zhenli Zhang1, Sharon C Glotzer1

  • 1Departments of Chemical Engineering and Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136.

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|October 20, 2017
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Summary
This summary is machine-generated.

Patchy particles self-assemble into diverse structures like chains and sheets. Precise patch design controls particle arrangement and assembly, enabling fabrication of complex structures.

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Area of Science:

  • Materials Science
  • Physical Chemistry
  • Computational Chemistry

Background:

  • Self-assembly is a fundamental process in nature and materials science.
  • Controlling self-assembly requires designing building blocks with specific interaction properties.

Purpose of the Study:

  • To investigate the self-assembly of particles with discrete interaction sites ('patches').
  • To explore how surface patch design influences the resulting structures.
  • To understand the thermodynamic transitions governing self-assembly.

Main Methods:

  • Utilizing molecular simulations to model particle interactions.
  • Designing various surface patch patterns on spherical particles.
  • Analyzing the emergent structures and phase transitions.

Main Results:

  • Formation of diverse structures including chains, sheets, rings, icosahedra, and more.
  • Two-dimensional sheets and icosahedra form via first-order transitions.
  • Chains form via continuous transitions, similar to equilibrium polymerization.
  • Patch selectivity dictates particle positioning and assembly outcomes.

Conclusions:

  • Patchy particles offer precise control over self-assembly.
  • Tailored surface patterns enable the fabrication of complex, ordered structures.
  • Patchy particles represent a novel class of building blocks for advanced materials.