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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Surface-confined [2 + 2] cycloaddition towards one-dimensional polymers featuring cyclobutadiene units.

Bay V Tran1, Tuan Anh Pham, Michael Grunst

  • 1Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands. tvanbay@gmail.com m.a.stohr@rug.nl.

Nanoscale
|November 17, 2017
PubMed
Summary

Researchers created novel 1D polymers using surface-confined [2+2] cycloaddition of pyrene. A crucial hydrogen treatment enabled byproduct removal and formation of 1,3-cyclobutadiene units for advanced molecular nanostructures.

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