Electrical resistivity and wave character of free electrons in amorphous and nanoglass Sc₇₅Fe₂₅

The residual electrical resistivity of metallic amorphous alloys, ρ ₀, is typically in the range 50 µΩ cm  <  ρ ₀  <  310 µΩ cm corresponding to a mean free path of conduction electrons of order a few interatomic distances. In crystalline metals with low defect levels such as Cu however, the residual electrical resistivity is about ρ ₀  ≈  1.54  ×  10^-2 µΩ cm, leading to extensive progression of free electrons through the crystalline material, of typically up to 4  ×  10⁶ nm. The relatively 'high' values for the electrical resistivity of distorted Sc₇₅Fe₂₅ alloys are discussed here within the framework of the wave character of electrons. The present investigation of amorphous and nanoglass Sc₇₅Fe₂₅ over the temperature range 1.9-320 K, focuses on clarification of the temperature dependence of the resistivity, ρ(T). These alloys systems, which show a range of behaviours for temperature dependent resistivity-including temperature independent residual resistivity, as well as positive and negative polarities for the slope dρ(T)/dT-are examined in detail.