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Updated: Feb 17, 2026
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Published on: February 6, 2020
Total synthesis of selaginpulvilins A and C
Bhavani Shankar Chinta1, Beeraiah Baire
1Department of Chemistry, Institute of Technology Madras, Chennai-600036, India. beeru@iitm.ac.in.
Abstract:
An efficient formal total synthesis of two compounds from the selaginpulvilin family of natural products, selaginpulvilin A and C, has been successfully achieved. The tetradehydro Diels-Alder (TDDA) reaction between an enyne and alkyne has been utilized for the creation of the necessary fluorene skeleton. Attempts at the conversion of selaginpulvilin A to selaginpulvilin B, F and H were unsuccessful.
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