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2,5-Diaryltellurophenes: Effect of Electron-Donating and Electron-Withdrawing Groups on their Optoelectronic
Noriyoshi Nagahora1, Shuhei Yahata1, Shoko Goto1
1Department of Chemistry, Faculty of Science, Fukuoka University , Jonan-ku, Fukuoka 814-0180, Japan.
Abstract:
The transformation of 1,2-bis(1-arylvinyl)ditellurides into 2,5-diaryltellurophenes by sequential ditelluride exchange and thermal intramolecular cyclization reactions is presented, and the optoelectronic properties of a series of 2,5-diaryltellurophenes with both electron-donating and electron-withdrawing aryl substituents are disclosed. Furthermore, the multicolored emissive tellurophenes in solution at room temperature have been demonstrated.
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