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Updated: Feb 13, 2026

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Introduction of carbon-boron atomic groups as an efficient strategy to boost formic acid production toward CO2
Yun Cao1, Zhigang Geng, Weiwei Chen
1Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China. zengj@ustc.edu.cn.
Abstract:
Introducing C-B diatomic groups in carbon-doped hexagonal boron nitride (h-BN) flakes resulted in high activity and selectivity for HCOOH in CO2 electroreduction. The activation of CO2 was prone to occur on B atoms while the activation of the proton occurred on C atoms. The volcano-type relation of Faradaic efficiency for HCOOH production over carbon content originates from the balance of H* and COOH* intermediates in carbon-doped h-BN catalysts.
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