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α-Ketocarbenium Ions Derived from Orthoquinone-Containing Polycyclic Aromatic Compounds

Kazuki Urakawa1, Yuta Kawabata1, Masaki Matsuda2

  • 1Division of Organic Chemistry, Department of Chemistry , Kumamoto University , 2-39-1 Kurokami, Chuo-ku , Kumamoto 860-8555 , Japan.

Organic Letters
|April 14, 2018
PubMed
Summary

Synthesized orthoquinone-containing polycyclic aromatic compounds form novel alpha-ketocarbenium ions. These ions exhibit unique absorption properties and are stabilized by aromatic conjugation and zigzag structures.

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