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Tuning Dihydrogen Bonds: Enhanced Solid-State Reactivity in a Dihydrogen-Bonded System with Exceptionally Short H⋅⋅⋅H
Radu Custelcean1, James E Jackson1
1Department of Chemistry, 513 Chemistry Building, Michigan State University, East Lansing, MI 48824 (USA), Fax: (517)353-1793.
Angewandte Chemie (International Ed. in English)
|May 2, 2018
Abstract:
Topochemical assembly of a covalent material can be achieved with the complex LiBH4 ⋅TEA (TEA=triethanolamine; section of structure shown), a dihydrogen-bonded system which has very short H⋅⋅⋅H contacts and high solid-state reactivity due to acidity enhancement in the OH groups by Li+ ion complexation.
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