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Updated: Feb 11, 2026

Crystallizing Membrane Proteins for Structure Determination using Lipidic Mesophases
Published on: November 21, 2010
Synthesis and Crystal Structure Analysis of Tetraphosphanylsilane and Identification of Tetraphosphanylgermane
Matthias Driess1, Christian Monsé1, Roland Boese2
1Lehrstuhl für Anorganische Chemie I der Universität, Fakultät für Chemie, Universitätsstrasse 150, D-44801 Bochum (Germany), Fax: (+49) 234-7094378.
Abstract:
Inversion-symmetric pairs, each with two weak P-H⋅⋅⋅P interactions, form molecules of Si(PH2 )4 in the crystal (see drawing). The title compounds are formed from ECl4 (E=Si,Ge) on reaction with [LiAl(PH2 )4 ] and could serve as single-source CVD precursors for phosphides.
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