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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
[(μ4 -H)Rh4 (PNNP)2 (CO)4 ]+ : A Novel Hydride Bridging Mode
Shukichi Tanaka1, Munetaka Akita1
1Chemical Resources Laboratory Tokyo Institute of Technology 4259 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan) Fax: (+81) 45-924-5230.
Abstract:
Metal-metal bonds are not essential for multiply bridging hydride ligands. A tetranuclear μ4 -hydride complex [(μ4 -H)Rh4 (PNNP)2 (CO)4 ]+ (PNNP=3,5-bis(diphenylphosphanylmethyl)pyrazolate), in which the quadruply bridging hydrido ligand holds the four isolated metal centers together to form a tetrahedral metal array, has been prepared and characterized by spectroscopic methods and single-crystal X-ray diffraction.
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