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Additive Manufacturing of Functionally Graded Ceramic Materials by Stereolithography
Published on: January 25, 2019
Rosa Lo Frano1, Monica Puccini2, Eleonora Stefanelli3
1Department of Civil and Industrial Engineering, University of Pisa, Largo Lucio Lazzarino 2, 56126 Pisa, Italy. rosa.lofrano@ing.unipi.it.
This study introduces a new way to make small ceramic pebbles for use in fusion reactors. These pebbles are made from lithium orthosilicate, a material that can capture neutrons and produce tritium, a key fuel for fusion. Current methods have issues like clumping and instability. The new drip casting method, developed by a university and an industry partner, avoids these problems. The pebbles produced are the right size and have good material properties. This method could help make reliable breeding blankets for future fusion reactors.
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Area of Science:
Background:
Fusion power reactors require breeding blankets to produce tritium, a key fuel. Current research focuses on materials that can capture neutrons and release tritium efficiently. Lithium orthosilicate has emerged as a candidate due to its neutron capture properties. However, its use is limited by challenges in manufacturing stable pebble forms. Existing methods have not yet met industrial standards. Agglomeration and chemical instability remain unresolved issues. These limitations hinder progress in developing reliable breeding blankets. The need for scalable and stable production methods is clear. This gap motivated the search for alternative fabrication techniques. A new drip casting method was proposed to address these challenges.
Purpose Of The Study:
This study aimed to develop a new manufacturing method for ceramic pebbles used in fusion reactors. The focus was on creating stable, appropriately sized pebbles from lithium orthosilicate. The goal was to improve upon existing methods that face issues like agglomeration. The drip casting method was selected as a potential solution. It was developed through a collaboration between DICI-University of Pisa and Industrie Bitossi. The method was designed to produce pebbles with diameters between 0.1 and 1 mm. The study sought to validate the feasibility of this new approach. It aimed to provide a scalable alternative for fusion reactor applications.
Main Methods:
The study utilized a drip casting method to produce ceramic pebbles. This method was developed through a joint effort between academic and industrial partners. The process involved forming lithium orthosilicate into spherical shapes. The pebbles were designed to have diameters in the 0.1–1 mm range. The method was tested for its ability to avoid agglomeration issues. Material properties were evaluated for stability and performance. The process was compared to existing industrial techniques. The method's potential for scaling to industrial levels was assessed.
Main Results:
The drip casting method successfully produced ceramic pebbles from lithium orthosilicate. The pebbles had diameters within the desired 0.1–1 mm range. The method showed improved stability compared to previous techniques. Agglomeration was reduced, indicating better chemical stability. The pebbles demonstrated low activation characteristics. They also showed low thermal expansion and high thermal conductivity. The method was found to be scalable for industrial production. These results suggest the method is a viable alternative for fusion applications.
Conclusions:
The drip casting method offers a promising alternative for producing ceramic pebbles. It addresses key manufacturing challenges such as agglomeration. The method produces pebbles with suitable size and material properties. The results support its potential for use in fusion reactors. The collaboration between academic and industrial partners was critical. The method meets the basic requirements for breeding blanket materials. Further testing is needed to confirm long-term stability. The study provides a foundation for future industrial development.
Lithium orthosilicate captures neutrons and produces tritium via the 6Li (n, t) 4He reaction.
It is a new technique developed by DICI-University of Pisa and Industrie Bitossi to form ceramic pebbles.
Pebbles between 0.1 and 1 mm are needed for optimal performance in breeding blankets.
It reduces agglomeration and improves chemical stability compared to existing methods.
Thermal conductivity, thermal expansion, and activation characteristics were assessed.
The researchers propose further testing to confirm long-term stability and scalability.