Transition-Metal-Catalyzed Decarbonylative Coupling Reactions: Concepts, Classifications, and Applications
Lin Guo1, Magnus Rueping1,2
1Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.
Abstract:
Transition metal-catalyzed decarbonylative coupling reactions have emerged as a powerful alternative to conventional cross-coupling protocols due to the advantages associated with the use of carbonyl-containing functionalities as coupling electrophiles instead of commonly used organohalides or sulfates. A wide variety of novel transformations based on this concept have been successfully achieved, including decarbonylative carbon-carbon and carbon-heteroatom bond forming reactions. In this Review, we summarize the recent progress in this field and present a comprehensive overview of metal-catalyzed decarbonylative coupling reactions with carbonyl derivatives.
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