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Effect of chitin nanofibrils on electrospinning of chitosan-based composite nanofibers
Irina P Dobrovolskaya1, Vladimir E Yudin1, Pavel V Popryadukhin1
1Institute of Macromolecular Compounds, Russian Academy of Sciences, 31 Bolshoy pr. VO, 199004 Saint-Petersburg, Russia; Peter the Great St. Petersburg Polytechnic University, Polytechnicheskaya ul. 29, 195251 Saint-Petersburg, Russia.
Abstract:
Electrical conductivity, surface tension and viscosity of chitosan-based composite nanofibers are reported. 20 wt.% of chitin nanofibrils introduced into a chitosan solution leads to increase in viscosity of the mixture; the effect of shear rate becomes more pronounced. This phenomenon is caused by the formation of cluster structures involving filler particles, and by orientation of chitin nanofibrils under the action of shear stresses in electromagnetic field. Presence of chitin facilitated formation of nanofibers in electric field and led to significant decrease in the amount of defects.
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