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Updated: Feb 9, 2026

Synthesis and Exfoliation of Discotic Zirconium Phosphates to Obtain Colloidal Liquid Crystals
Published on: May 25, 2016
Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic
Alexander Ovchinnikov1, Julien P A Makongo, Svilen Bobev
1Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA. bobev@udel.edu.
Abstract:
The binary bismuthides Nd3Bi7 and Sm3Bi7 were synthesized and structurally characterized for the first time. The results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.
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