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Published on: October 18, 2015
Understanding the Molecule-Electrode Interface for Molecular Spintronic Devices: A Computational and Experimental
Lidia Rosado Piquer1,2, Raquel Royo Sánchez3, E Carolina Sañudo4,5
1Departament de Química Inorgànica, Secció de Química Inorgànica; C/Martí i Franqués 1-11, 08028 Barcelona, Spain. li.rosado.p@gmail.com.
Abstract:
A triple-decker SYML-Dy2 single-molecule magnet (SMM) was synthetized and grafted onto the surface of iron oxide nanoparticles (IO-NPs) coated by an oleic acid monolayer. The magnetism of the SYML-Dy2 complex, and the hybrid system, NP-Dy2, were studied by a superconducting quantum interference device (SQUID). Density functional theory (DFT) calculations were carried out to study both the energetics of the interaction between SYML-Dy2 complex to the organic capping, and the assembly presented by the oleic acid chains.
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