Mesoporous TiO₂ with WO₃ functioning as dopant and light-sensitizer: A highly efficient photocatalyst for degradation...

The suitable doping or modification on TiO₂ holds promise for improving charge separation and extending light absorption range. Here, WO₃ modifying reduced band gap mesoporous TiO₂ (WO₃/RM-TiO₂) due to WO₃ doping was successfully fabricated by immersing mesoporous TiO₂ nanoparticles in the peroxotungstic acid sol with controllable reaction time (0-1 h). The W⁶⁺ ions were first incorporated into the TiO₂ lattice to form WOTi bonds, resulting in the formation of WO₃ doping TiO₂. Then, WO₃ nanoparticles gradually formed and attached on the TiO₂ surface, constructing a novel heterojunction catalyst with WO₃ serving as both dopant and light-sensitizer for TiO₂. Photocatalytic activity of the resulting WO₃/RM-TiO₂ depends on the immersing duration in the peroxotungstic acid. The BET analysis shows that 0.5 h-WO₃/RM-TiO₂ has the largest pore volume of 0.491 cm³ g^-1 and the highest surface area of 82.3 m² g^-1, whereas these values decline with prolonged immersing duration. As expected, the optimal efficiency in removing p-nitrophenol (PNP) is achieved over 0.5 h-WO₃/RM-TiO₂ under visible light irradiation, which is 2.33 times that of the unmodified M-TiO₂. This should be attributed to the suitable WO₃ doping and WO₃ modification.