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Updated: Feb 7, 2026

Facile Synthesis of Worm-like Micelles by Visible Light Mediated Dispersion Polymerization Using Photoredox Catalyst
Published on: June 8, 2016
Facile synthesis of polycyclic metallaarynes
Wenqing Ruan1, Tsz-Fai Leung1, Chuan Shi1
1Department of Chemistry , Hong Kong University of Science and Technology , Clear Water Bay , Kowloon , Hong Kong . Email: chwill@ust.hk ; Email: chzlin@ust.hk ;
Abstract:
Metalla-analogs of polycyclic arynes represent an interesting class of metallaaromatics with a formal M[triple bond, length as m-dash]C bond within the ring. The first examples of a bicyclic β-metallaaryne and tricyclic metallaarynes, including a metallaanthracyne and a metallaphenanthryne, were obtained in good yields by reactions of OsCl2(PPh3)3 with alkyne-functionalized phosphorus ylides.
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