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Generation of stannabenzenes and their monomer-dimer equilibration
Yoshiyuki Mizuhata1, Shiori Fujimori, Naoya Noda
1Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan. tokitoh@boc.kuicr.kyoto-u.ac.jp mizu@boc.kuicr.kyoto-u.ac.jp.
Abstract:
Stannabenzene has not been isolated so far because of its high reactivity. In order to synthesize and isolate a stable stannabenzene, we have introduced two steric protection groups, the Tbt (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl) or the Bbt (2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl) group on the tin atom and the t-butyl group on the 2-position, to the stannabenzene skeleton. Such a combination of steric protection groups was found to suppress the dimerization of stannabenzene to some extent, giving an equilibrated mixture of the corresponding stannabenzene and its dimer.
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