Light-induced mechanical response in crosslinked liquid-crystalline polymers with photoswitchable glass transition...

Energy conversion of light into mechanical work is of fundamental interest in applications. In particular, diligent molecular design on nanoscale, in order to achieve efficient photomechanical effects on macroscopic scale, has become one of the most interesting study topics. Here, by incorporating a "photomelting" azobenzene monomer crosslinked into liquid crystalline (LC) networks, we generate photoresponsive polymer films that exhibit reversible photoswitchable glass transition temperatures (T_g) at room temperature (~20 °C) and photomechanical actuations under the stimulus of UV/visible light. The trans-to-cis isomerization of azo chromophores results in a change in T_g of the crosslinked LC polymers. The T_g of the polymer network is higher than room temperature in the trans-form and lower than room temperature in the cis-form. We demonstrate the photoswitchable T_g contribute to the photomechanical bending and a new mechanism for photomechanical bending that attributes the process to an inhomogeneous change in T_g of the film is proposed.