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Updated: Feb 6, 2026

Low Pressure Vapor-assisted Solution Process for Tunable Band Gap Pinhole-free Methylammonium Lead Halide Perovskite Films
Published on: September 8, 2017
Lead-Free Solar Cells based on Tin Halide Perovskite Films with High Coverage and Improved Aggregation
Jiewei Liu1, Masashi Ozaki1, Shinya Yakumaru1
1Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
Abstract:
Two simple methods to improve tin halide perovskite film structure are introduced, aimed at increasing the power conversion efficiency of lead free perovskite solar cells. First, a hot antisolvent treatment (HAT) was found to increase the film coverage and prevent electrical shunting in the photovoltaic device. Second, it was discovered that annealing under a low partial pressure of dimethyl sulfoxide vapor increased the average crystallite size. The topographical and electrical qualities of the perovskite films are substantively improved as a result of the combined treatments, facilitating the fabrication of tin-based perovskite solar cell devices with power conversion efficiencies of over 7 %.
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