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Updated: Feb 6, 2026

Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials
Published on: May 15, 2015
BODIPY-based Carbonaceous Materials for High Performance Electrical Capacitive Energy Storage
De-Gao Wang1, Huan Wang1, Min Song1
1State Key Laboratory of Power Metallurgy, Department of Polymer Materials and Engineering, Central South University, Changsha, Hunan, 410083, China.
This study introduces multi-light element doping in carbon materials for enhanced supercapacitor performance. The developed boron, nitrogen, and fluorine-doped carbon material exhibits excellent capacitance and stability.
Area of Science:
- Materials Science
- Electrochemistry
- Nanotechnology
Background:
- Heteroatom doping is key for tuning carbon material properties.
- Multi-light element doping in carbon materials is underexplored for energy storage.
Purpose of the Study:
- To develop novel porous organic polymers doped with boron, nitrogen, and fluorine.
- To investigate the electrochemical performance of derived carbonaceous materials for supercapacitor applications.
Main Methods:
- Synthesis of a porous organic polymer (BPOP) with boron, nitrogen, and fluorine.
- Carbonation and KOH activation to create carbonaceous materials.
- Electrochemical measurements using three- and two-electrode systems.
Main Results:
- KOH-activated BPOP (BPOP-700A) achieved a specific capacitance of 408 F/g.
- Achieved an energy density over 19.2 Wh/kg in an aqueous electrolyte.
- Demonstrated excellent rate capability and 95% capacitance retention over 10,000 cycles.
Conclusions:
- Multi-light element doping (B, N, F) significantly enhances supercapacitor performance.
- Porous structure and pore size distribution contribute to superior electrochemical properties.
- This work provides insights for designing advanced carbon materials for supercapacitors.
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