Surface modified halloysite nanotubes: A flexible interface for biological, environmental and catalytic applications

Halloysite Nanotubes (HNTs) are clay minerals that possess unique chemical composition and a tubular structure due to which, they have recently emerged as a potential nanomaterial for umpteen applications. Over the years, the myriad applications of HNT have been realized through the surface modification of HNT, which involves the modification of nanotube's inner lumen and the outer surface with different functional compounds. The presence of aluminum and silica groups on the inner and outer surface of HNT enhance the interfacial relationship of the nanotube with different functional agents. Compounds such as alkalis, organosilanes, polymers, compounds of biological origin, surfactants and nanomaterials have been used for the modification of the inner lumen and the outer surface of HNT. The strategies change the constitution of HNT's surface either through micro-disintegration of the surface or by introducing additional functional groups on the surface, which further enhances their potential to be used as a flexible interface for different applications. In this review, the different surface modification strategies of the outer surface and the inner lumen that have been employed over the years have been discussed. The biological, environmental and catalytic applications of these surface modified HNTs with such versatile interface in the past two years have been elaborately discussed as well.