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Updated: Feb 4, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Ruthenium(IV) Intermediates in C-H Activation/Annulation by Weak O-Coordination

Yu-Feng Liang1, Long Yang1, Torben Rogge1

  • 1Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077, Gottingen, Germany.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|September 26, 2018
PubMed
Summary

Ruthenium(IV) complexes enable C-H/O-H activations. This study demonstrates efficient synthesis of isocoumarins using sulfoxonium ylides and benzoic acids via a ruthenium-catalyzed BIES-C-H activation pathway.

Keywords:
C−H activationmechanismruthenium(IV)sulfoxonium ylideweak coordinationylides

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