Simple One-Pot Preparation of a Rapid Response AIE Fluorescent Metal-Organic Framework

Luminogenic materials, particularly those that have turn-on response by sensing the analytes, are highly regarded as optical instruments, sensing material, fluorescent probes, etc. However, most of these materials are only usable in dilute form and often show the self-quenching effect at high concentrations. The use of light-emitting AIE-based materials (aggregation-induced emission) is the solution of this problem. The rigid structure of these active fluorescence ligands, which contains several aromatic rings attached to each other, does not lose its fluorescence properties by increasing the concentration. Unlike other AIE ligands, which have a complex or multistep synthetic route, here, we present a simple one-pot method for in situ synthesis of the AIE ligand and the metal-organic framework (MOF) contained therein. Presence of metal nodes having varied outer-shell electron configurations affects the fluorescence intensity of these materials and, thus, both high and low emissive "turn on" MOFs were readily acquired. Based on the possible interactions between the free nitrogens on the ligand and the phenolic compounds, the MOFs enable highly selective and sensitive detection of phenol derivatives in several seconds with low detection limits (less than 65 nM for 4-aminophenol and 120 nM for phenol) through turn-on emission fluorescence.