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Development of Alkaline-Activated Self-Leveling Hybrid Mortar Ash-Based Composites
Luís Urbano Durlo Tambara Júnior1, Malik Cheriaf2, Janaíde Cavalcante Rocha3
1Laboratory of Waste Valorization and Sustainable Materials (ValoRes), Department of Civil Engineering, PPGEC, Federal University of Santa Catarina (USFC), Campus Trindade, 88040-900 Florianópolis, SC, Brazil. luis.tambara@posgrad.ufsc.br.
Abstract:
This study investigated the reactivity properties of self-leveling hybrid alkali-activated cements, such as ordinary Portland cement (OPC) and its residual precursors, coal bottom ash (BA), and rice husk ash (RHA). Due to the relatively low reactivity of BA, binary mixes were produced with OPC using contents of 2.5⁻30% in the treated BA samples. Furthermore, ternary mixes were prepared in proportions of 25%, 50%, and 75% with RHA as a replacement material for the OPC (mix with 90%:10% BA:OPC). For all of the mixes the spreading behaviors were fixed to obtain a self-levelling mortar, and dimensional changes, such as curling and shrinkage, were performed. Mortars with 30% OPC reached a compressive strength of 33.5 MPa and flexural strength of 7.53 MPa. A scanning electron microscope (SEM) and X-ray powder diffraction (XRD) were used to indicate the formation of N-A-S-H and a (N,C)-A-S-H gel, similar to the gel with trace of calcium. The best performance was achieved when the binary mix produced 10% OPC. A hybrid mortar of OPS-BA presented 10 times lower susceptibility to curling than an OPC mortar. The results showed that both ashes reduced the shrinkage and curling phenomena.
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