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Published on: November 25, 2009
Fine-tuning the assemblies of carbon nanodots and porphyrins
Tobias Scharl1, Alejandro Cadranel, Philipp Haines
1Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Germany. dirk.guldi@fau.de.
Abstract:
We present charge-transfer assemblies of electron accepting, pressure-synthesized carbon nanodots (pCNDs) and an electron donating porphyrin. Amidine derivatization of the porphyrin allows for hydrogen bonding interactions with the carboxyl groups on the surface of pCNDs, which drive the formation of the assembly. Upon photoexcitation, this electron donor-acceptor supramolecular construct features ultrafast charge separation, and subsequent charge recombination in 27 ps.
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