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Published on: August 26, 2010
Molecular electronic spin qubits from a spin-frustrated trinuclear copper complex
Benjamin Kintzel1, Michael Böhme1, Junjie Liu2
1Institut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität Jena, Humboldtstraße 8, 07745 Jena, Germany. sekr.plass@uni-jena.de.
Abstract:
The trinuclear copper(ii) complex [Cu3(saltag)(py)6]ClO4 (H5saltag = tris(2-hydroxybenzylidene)triaminoguanidine) was synthesized and characterized by experimental as well as theoretical methods. This complex exhibits a strong antiferromagnetic coupling (J = -298 cm-1) between the copper(ii) ions, mediated by the N-N diazine bridges of the tritopic ligand, leading to a spin-frustrated system. This compound shows a T2 coherence time of 340 ns in frozen pyridine solution, which extends to 591 ns by changing the solvent to pyridine-d5. Hence, the presented compound is a promising candidate as a building block for molecular spintronics.
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