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Updated: Feb 3, 2026

Basic Research in Plasma Medicine - A Throughput Approach from Liquids to Cells
Published on: November 17, 2017
Cellulose defibrillation and functionalization by plasma in liquid treatment
Sorin Vizireanu1, Denis Mihaela Panaitescu2, Cristian Andi Nicolae3
1National Institute for Laser, Plasma and Radiation Physics, Atomistilor 409, Magurele, Bucharest, Ilfov, 077125, Romania.
Submerged liquid plasma (SLP) treatment effectively modifies microcrystalline cellulose (MCC), enhancing its defibrillation and surface functionalization. This plasma-activated cellulose improves biopolymer composites
Area of Science:
- Materials Science
- Surface Chemistry
- Polymer Science
Background:
- Submerged liquid plasma (SLP) is an emerging technique for powder material modification.
- Current applications of SLP are primarily on carbonaceous materials, with limited exploration for cellulose modification.
- Cellulose modification holds potential for developing cost-effective and eco-friendly biomaterials.
Purpose of the Study:
- To investigate the modification of microcrystalline cellulose (MCC) using submerged liquid plasma (SLP) combined with ultrasonication.
- To explore the effects of inert (argon) and reactive (argon:oxygen, argon:nitrogen) plasma gases on MCC.
- To evaluate the impact of plasma-treated MCC on the properties of poly(3-hydroxybutyrate) (PHB) composites.
Main Methods:
- Microcrystalline cellulose (MCC) dispersions were treated using SLP in various gas atmospheres (argon, argon:oxygen, argon:nitrogen).
- Ultrasonication was applied in conjunction with SLP treatments.
- Surface characterization was performed using X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR).
Main Results:
- SLP treatment significantly enhanced the defibrillation of MCC.
- Surface functionalization of MCC with oxygen or nitrogen moieties was confirmed by XPS and FTIR.
- Poly(3-hydroxybutyrate) composites incorporating plasma-modified cellulose fibers exhibited improved thermal stability and mechanical properties compared to pristine PHB.
Conclusions:
- SLP processing is an effective method for activating cellulose, promoting defibrillation and surface functionalization.
- Plasma-modified cellulose demonstrates potential as a reinforcing agent for biopolymers.
- This technique offers a novel approach for enhancing the performance of biopolymer composites.
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