MWCNTs-Supported Pd(II) Complexes with High Catalytic Efficiency in Oxygen Reduction Reaction in Alkaline Media
Maurizio Passaponti1, Matteo Savastano1,2, M Paz Clares3
1Department of Chemistry "Ugo Schiff" , University of Florence , via della Lastruccia 3 , 50019 Sesto Fiorentino , Italy.
Abstract:
We report here the remarkable catalytic efficiency observed for two Pd(II) azamacrocyclic complexes supported on multiwalled carbon nanotubes (MWCNTs) toward oxygen reduction reactions. Beyond a main (>90%) 4e- process and an onset potential close to or better than those of commercial Pt electrodes, the MWCNTs functionalization strategy, aimed at chemically defined Pd(II)-based catalytic centers, allowed the half-cell to exceed the proton-exchange-membrane fuel-cell reference/target mass activity efficiency set by the U.S. Department of Energy for 2020 (440 mA/mgPGM at 0.9 V vs reversible hydrogen electrode).
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