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Updated: Feb 2, 2026

Soft Lithographic Functionalization and Patterning Oxide-free Silicon and Germanium
Published on: December 16, 2011
Non-Lithographic Silicon Micromachining Using Inkjet and Chemical Etching
Sasha Hoshian1, Cristina Gaspar2, Teemu Vasara3
1Department of Chemistry and Materials Science, School of Chemical Technology, Aalto University, FI02150 Espoo, Finland. sasha.hoshian@aalto.fi.
We developed INKMAC, a novel inkjet printing and metal-assisted chemical etching method for patterning silicon without vacuum or lithography. This technique creates silicon microfluidic channels and cavities, enabling diverse applications.
Area of Science:
- Materials Science
- Microfabrication
- Nanotechnology
Background:
- Traditional silicon patterning methods often require complex lithography and vacuum processes.
- Developing cost-effective, scalable, and versatile patterning techniques is crucial for microfluidics and nanotechnology.
Purpose of the Study:
- To introduce a novel, non-lithographical, and vacuum-free method for patterning silicon using inkjet printing and metal-assisted chemical etching (INKMAC).
- To demonstrate the fabrication of silicon microfluidic channels and cavities with controlled dimensions and aspect ratios.
- To explore the potential of the patterned silicon as a template for creating superhydrophobic surfaces.
Main Methods:
- Inkjet printing of commercial silver ink onto a silicon surface to define catalytic patterns.
- Metal-assisted chemical etching (MaCE) to form silicon nanowires in the printed pattern.
- Potassium hydroxide (KOH) wet etching to remove nanowires and create cavities/channels.
Main Results:
- Successfully patterned silicon using the INKMAC method, creating microfluidic channels (50-100 µm width, 10-40 µm depth) and cavities (30 µm diameter, 60 µm depth).
- Achieved aspect ratios close to one for channels and up to two for cavities.
- Demonstrated the potential for polymer replication to create superhydrophobic surfaces from the patterned silicon.
Conclusions:
- The INKMAC method offers a simple, scalable, and versatile approach for silicon microfabrication.
- This technique enables the creation of functional microfluidic devices and templates for advanced surface engineering.
- INKMAC presents a promising alternative to conventional patterning methods for various scientific and technological applications.
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